Coverart for item
The Resource Activation and functionalization of C-H bonds, Karen I. Goldberg, Alan S. Goldman, editors ; sponsored by the ACS Division of Inorganic Chemistry, Inc, (electronic book)

Activation and functionalization of C-H bonds, Karen I. Goldberg, Alan S. Goldman, editors ; sponsored by the ACS Division of Inorganic Chemistry, Inc, (electronic book)

Label
Activation and functionalization of C-H bonds
Title
Activation and functionalization of C-H bonds
Statement of responsibility
Karen I. Goldberg, Alan S. Goldman, editors ; sponsored by the ACS Division of Inorganic Chemistry, Inc
Contributor
Subject
Genre
Language
eng
Summary
Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules. -- publisher's description
Cataloging source
DLC
Illustrations
illustrations
Index
index present
Literary form
non fiction
http://library.link/vocab/relatedWorkOrContributorDate
  • 1962-
  • 1958-
  • 2002 :
http://library.link/vocab/relatedWorkOrContributorName
  • Goldberg, Karen I.
  • Goldman, Alan S.
  • American Chemical Society
  • American Chemical Society
Series statement
ACS symposium series
Series volume
885
http://library.link/vocab/subjectName
  • Hydrocarbons
  • Activation (Chemistry)
  • Organometallic compounds
  • Catalysis
Label
Activation and functionalization of C-H bonds, Karen I. Goldberg, Alan S. Goldman, editors ; sponsored by the ACS Division of Inorganic Chemistry, Inc, (electronic book)
Instantiates
Publication
Bibliography note
Includes bibliographical references and indexes
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Preface -- 1. Organometallic C-H Bond Activation: An Introduction / Alan S. Goldman and Karen I. Goldberg -- Oxidative Addition Reactions -- 2. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions / Steven R. Klei ... [et al.] -- 3. Alkane Complexes as Intermediates in C-H Bond Activation Reactions / William D. Jones ... [et al.] -- 4. C-C versus C-H Bond Oxidative Addition in PCX (X=P,N,O) Ligand Systems: Facility, Mechanism, and Control -- 5. Kinetic and Equilibrium Deuterium Isotope Effects for C-H Bond Reductive Elimination and Oxidative Addition Reactions Involving the Ansa-Tungstenocene Methyl-Hydride Complex [Me2Si(C2Me4)2]W(Me)H / Kevin E. Janak, David G. Churchill, and Gerard Parkin -- 6. Alkane C-H Bond Activation by O-Doner Ir Complexes / Guarav Bhalla ... [et al.] -- 7. Lanthanide Complexes: Electronic Structure and H-H, C-H, and Si-H Bond Activation from a DFT Perspective / Lionel Perrin, Laurent Maron, and Odile Eisenstein -- C-H Bond Activations in Organic Synthesis, Alkane Dehydrogenation, and Related Chemistry -- 8. Catalytic, Thermal, Regioselective Functionalization of Alkanes and Arenes with Borane Reagents / John F. Hartwig -- 9. C-H Bond Functionalization in Complex Organic Synthesis / Dalibor Sames -- 10. Pincer and Chelate NR-Heterocyclic Carbene Complexes of Rh, Ir, and Pd: Synthetic Routes, Dynamics, Catalysis, Abnormal Binding, and Counterion Effects / Anthony R. Chianese and Robert H. Crabtree -- 11. Sequential Hydrocarbon C-H Bond Actvations by 16-Electron Organometallic Complexes of Molybdenum and Tungsten / Peter Legzdins and Craig B. Pamplin -- 12. Alkane Transfer-Dehydrogenation Catalyzed by a Pincer-Ligated Iridium Complex / Alan S. Goldman ... [et al.] -- 13. DFT Calculations on the Mechanism of (PCP)Ir-Catalyzed Acceptorless Dehydrogenation of Alkanes: Realistic Computational Models and Free Energy Considerations / Karsten Krogh-Jespersen, Margaret Czerw, and Alan S. Golman -- 14. Double Cyclometalation: Implications for C-H Oxidative Addition with PCP Pincer Compounds of Iridium / Hani A.Y. Mohammad ... [et al.] -- 15. C-H Bond Activation at Pt(II): A Route to Selective Alkane Oxidation?, Alan F. Heyduk ... [et al.] -- 16. Competitive Trapping of Equilibrating Pt(IV) Hydridoalkyl and Pt(II) Alkane Complexes: A Valuable Tool for the Mechanistic Investigation of C-H Activation Reactions / Mats Tilset ... [et al.] -- 17. Mechanisms of Reactions Related to Selective Alkane Oxidation by Pt Complexes / Jennifer L. Look, Ulrich Fekl, and Karen I. Goldberg -- 18. Hydrocarbon C-H Bond Activation with Tp'Pt Complexes / Cynthia M. Norris and Joseph L. Templeton -- 19. C-H Bond Activation with Neutral Platinum Methyl Complexes / Carl N. Iverson ... [et al.] -- 20. Issues Relevant to C-H Activation at Platinum(II): Comparative Studies between Cationic, Zwitterionic, and Neutral Platinum(II) Compounds in Benzene Solution / Jonal C. Peters ... [et al.] -- Oxidations -- 21. Non-Organometallic Mechanisms for C-H Bond Oxidation: Hydrogen Atom versus Electron versus Hydride Transfer / James M. Mayer ... [et al.] -- 22. Oxidation of Organic Molecules with Molecular Oxygen Catalyzed by Herometallic Complexes / Patricia A. Shapley -- 23. Catalytic Hydrocarbon Oxidations Involving Coreductants / Joseph E. Remias and Ayusman Sen -- 24. New Applications of Electrophilic Aromatic C-H Activation with Metal Trifluoroacetates / Vladimir V. Grushin ... [et al.] -- 25. Reengineering of Organic-Based Metal Active Sites for Oxidations and Oxygenations / Sergiu M. Gorun -- Author Index-- Subject Index
Dimensions
24 cm.
Extent
xiv, 440 p.
Form of item
electronic
Isbn
9780841238497
Lccn
2004041123
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
ill.
Reproduction note
Electronic Resource.
Label
Activation and functionalization of C-H bonds, Karen I. Goldberg, Alan S. Goldman, editors ; sponsored by the ACS Division of Inorganic Chemistry, Inc, (electronic book)
Publication
Bibliography note
Includes bibliographical references and indexes
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
Preface -- 1. Organometallic C-H Bond Activation: An Introduction / Alan S. Goldman and Karen I. Goldberg -- Oxidative Addition Reactions -- 2. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions / Steven R. Klei ... [et al.] -- 3. Alkane Complexes as Intermediates in C-H Bond Activation Reactions / William D. Jones ... [et al.] -- 4. C-C versus C-H Bond Oxidative Addition in PCX (X=P,N,O) Ligand Systems: Facility, Mechanism, and Control -- 5. Kinetic and Equilibrium Deuterium Isotope Effects for C-H Bond Reductive Elimination and Oxidative Addition Reactions Involving the Ansa-Tungstenocene Methyl-Hydride Complex [Me2Si(C2Me4)2]W(Me)H / Kevin E. Janak, David G. Churchill, and Gerard Parkin -- 6. Alkane C-H Bond Activation by O-Doner Ir Complexes / Guarav Bhalla ... [et al.] -- 7. Lanthanide Complexes: Electronic Structure and H-H, C-H, and Si-H Bond Activation from a DFT Perspective / Lionel Perrin, Laurent Maron, and Odile Eisenstein -- C-H Bond Activations in Organic Synthesis, Alkane Dehydrogenation, and Related Chemistry -- 8. Catalytic, Thermal, Regioselective Functionalization of Alkanes and Arenes with Borane Reagents / John F. Hartwig -- 9. C-H Bond Functionalization in Complex Organic Synthesis / Dalibor Sames -- 10. Pincer and Chelate NR-Heterocyclic Carbene Complexes of Rh, Ir, and Pd: Synthetic Routes, Dynamics, Catalysis, Abnormal Binding, and Counterion Effects / Anthony R. Chianese and Robert H. Crabtree -- 11. Sequential Hydrocarbon C-H Bond Actvations by 16-Electron Organometallic Complexes of Molybdenum and Tungsten / Peter Legzdins and Craig B. Pamplin -- 12. Alkane Transfer-Dehydrogenation Catalyzed by a Pincer-Ligated Iridium Complex / Alan S. Goldman ... [et al.] -- 13. DFT Calculations on the Mechanism of (PCP)Ir-Catalyzed Acceptorless Dehydrogenation of Alkanes: Realistic Computational Models and Free Energy Considerations / Karsten Krogh-Jespersen, Margaret Czerw, and Alan S. Golman -- 14. Double Cyclometalation: Implications for C-H Oxidative Addition with PCP Pincer Compounds of Iridium / Hani A.Y. Mohammad ... [et al.] -- 15. C-H Bond Activation at Pt(II): A Route to Selective Alkane Oxidation?, Alan F. Heyduk ... [et al.] -- 16. Competitive Trapping of Equilibrating Pt(IV) Hydridoalkyl and Pt(II) Alkane Complexes: A Valuable Tool for the Mechanistic Investigation of C-H Activation Reactions / Mats Tilset ... [et al.] -- 17. Mechanisms of Reactions Related to Selective Alkane Oxidation by Pt Complexes / Jennifer L. Look, Ulrich Fekl, and Karen I. Goldberg -- 18. Hydrocarbon C-H Bond Activation with Tp'Pt Complexes / Cynthia M. Norris and Joseph L. Templeton -- 19. C-H Bond Activation with Neutral Platinum Methyl Complexes / Carl N. Iverson ... [et al.] -- 20. Issues Relevant to C-H Activation at Platinum(II): Comparative Studies between Cationic, Zwitterionic, and Neutral Platinum(II) Compounds in Benzene Solution / Jonal C. Peters ... [et al.] -- Oxidations -- 21. Non-Organometallic Mechanisms for C-H Bond Oxidation: Hydrogen Atom versus Electron versus Hydride Transfer / James M. Mayer ... [et al.] -- 22. Oxidation of Organic Molecules with Molecular Oxygen Catalyzed by Herometallic Complexes / Patricia A. Shapley -- 23. Catalytic Hydrocarbon Oxidations Involving Coreductants / Joseph E. Remias and Ayusman Sen -- 24. New Applications of Electrophilic Aromatic C-H Activation with Metal Trifluoroacetates / Vladimir V. Grushin ... [et al.] -- 25. Reengineering of Organic-Based Metal Active Sites for Oxidations and Oxygenations / Sergiu M. Gorun -- Author Index-- Subject Index
Dimensions
24 cm.
Extent
xiv, 440 p.
Form of item
electronic
Isbn
9780841238497
Lccn
2004041123
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Other physical details
ill.
Reproduction note
Electronic Resource.

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